𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Determination of the metal-hydrogen and metal-methyl bond dissociation energies of the second-row, Group 8 transition metal cations

✍ Scribed by Mandich, M. L.; Halle, L. F.; Beauchamp, J. L.


Book ID
127300842
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
1024 KB
Volume
106
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Determination of metal-hydrogen bond dis
✍ Amy E. Stevens; J.L. Beauchamp πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 415 KB

ICR trapped ion techniques are used to examine the kinetics of proton transfer from MnH+ (formed as a fragment ion from HMn(CO)s by electron impact) to bases of varymg strength. Deprotonation is rapid with bases whose proton afflnity exceeds 196 f 3 kcal mol-\* \_ This value for PA (Mn) yields the h

Substituent Effects on the Bond-Dissocia
✍ Katrin Schroeter; Ralf Wesendrup; Helmut Schwarz πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 508 KB

The bond-dissociation energies (BDEs) of more than twenty areneΟͺM + complexes (M = Cr, Fe, Co) have been studied by mass spectrometry, using the kinetic method. With minor exceptions, the same relative order of BDEs is found for the three metals and the series of substituted arenes: electrondonating

A comparison of the bonding in the secon
✍ Per E.M. Siegbahn πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 867 KB

Calculations including electron correlation of all valence electrons have been performed for the sequence of second-row transition-metal oxides and carbenes. For the atoms to the right the bond strengths of the carbenes and the oxides are similar while for the atoms to the lefi the oxide bond streng