The rate coefficient, k , of the reaction H,O + CN + HCN + OH has been determined in the temperature range 2460-2840 K using a shock tube technique. C2N2-H20-Ar mixtures were heated behind incident shock waves and the CN and OH concentration time histories were monitored simultaneously using broad-b
Determination of the High-Pressure Limiting Rate Coefficient and the Enthalpy of Reaction for OH + SO 2
β Scribed by Blitz, Mark A.; Hughes, Kevin J.; Pilling, Michael J.
- Book ID
- 126301775
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 116 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Rate coefficients of the title reaction R 31 (SO 2 + O + M β SO 3 + M) and R 56 (SO 2 + HO 2 β SO 3 + OH), important in the conversion of S(IV) to S(VI), were obtained at T = 970-1150 K and Ο ave = 16.2 ΞΌmol cm -3 behind reflected shock waves by a perturbation method. Shockheated H 2 /O 2 /Ar mixtur
The rate coefficient of the reaction H + CO z ~ CO + OH (1) was measured using OH concentration measurements in shock-heated N20-H2-CO 2 mixtures and through the inhibiting effect of CO 2 on methane ignition. For 2170 < T < 3150 K the two methods give concordant results and imply k I = 2.0 Γ 1014exp
## Abstract The rate coefficient of the reaction has been determined in the temperature range of 2700β3500 K using a shock tube technique. C~2~N~2~ο£ΏH~2~ο£ΏAr mixtures were heated behind incident shock waves and the earlyβtime CN history was monitored using broadβband absorption spectroscopy. The ra