Determination of the Ground-State Dissociation Constant by Fluorometric Titration
β Scribed by Kowalczyk, Andrzej; Boens, Noel; Van den Bergh, Viviane; De Schryver, Frans C.
- Book ID
- 117997749
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 638 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
Nonlogarithmic titration curves may be used to determine thermodynamic dissociation constants in addition to measuring the purity of the substance titrated and estimating the accuracy of the data. Equations are derived and methods pro osed for carrying out these determinations with any monoprotic sp
A test based on time-resolved fluorescence experiments is proposed to assess the interference of an excited-state reaction with the fluorimetric determination of the ground-state dissociation constant Kd of ion [symbol: see text] fluorescent indicator complexes. If an inflection point occurs in the