Determination of the cis-trans isomerization barrier of enalaprilat by dynamic capillary electrophoresis and computer simulation
β Scribed by Oliver Trapp; Gabriele Trapp; Volker Schurig
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 92 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0173-0835
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π SIMILAR VOLUMES
Cis and trans isomers of tramadol hydrochloride were separated by capillary zone electrophoresis (CZE) in a fused-silica capillary with 40 mmol/L of borate as a carrier. The sample concentration-peak area plots were straight lines in the range 10-250 g/mL for both isomers. Based on the electropherog
## Abstract We synthesized numerous new monosubstituted dioxa[11]βparacyclophanes, which are planarβchiral atropisomers due to the hindered rotation of the bridge about the aromatic plane, and we were able to resolve the enantiomers of these compounds by enantioselective gas chromatography with sel