Determination of the Absolute Propagation Rate Constants in Polymerization with Reversible Aggregation of Active Centers
β Scribed by Duda, Andrzej; Penczek, Stanislaw
- Book ID
- 118126321
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 483 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Claims have recently been made that absolute rate constants for chain propagation of the unassociated active centers can be made in systems where a high degree of association is present. Anionic polymerization of styrene in nonpolar solvents with lithium as counterion is a typical case. The conditio
Polymerization inhibition with radioactive carbon monoxide was used to determine the number of active centers (C,) and the propagation rate constant (k,) in the isospecific polymerization of propene with the catalytic system TiCl,/diisobutyl phthalate/MgC1,-A1Et,-PhSi(OEt)3. The presence of hydrogen