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Determination of the Absolute Propagation Rate Constants in Polymerization with Reversible Aggregation of Active Centers

✍ Scribed by Duda, Andrzej; Penczek, Stanislaw


Book ID
118126321
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
483 KB
Volume
27
Category
Article
ISSN
0024-9297

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Comments on the determination of absolut
✍ S. Bywater πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 127 KB πŸ‘ 1 views

Claims have recently been made that absolute rate constants for chain propagation of the unassociated active centers can be made in systems where a high degree of association is present. Anionic polymerization of styrene in nonpolar solvents with lithium as counterion is a typical case. The conditio

Number of active centers and propagation
✍ Gennadii D. Bukatov; Valerii S. Goncharov; Vladimir A. Zakharov πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 409 KB

Polymerization inhibition with radioactive carbon monoxide was used to determine the number of active centers (C,) and the propagation rate constant (k,) in the isospecific polymerization of propene with the catalytic system TiCl,/diisobutyl phthalate/MgC1,-A1Et,-PhSi(OEt)3. The presence of hydrogen