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Determination of the absolute configuration and the first total synthesis of (−)- and (+)-linderol A

✍ Scribed by Masayuki Yamashita; Takashi Shimizu; Ikuo Kawasaki; Shunsaku Ohta


Book ID
108283795
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
281 KB
Volume
15
Category
Article
ISSN
0957-4166

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The first total synthesis of putaminoxin
✍ Gowravaram Sabitha; K. Yadagiri; R. Swapna; J.S. Yadav 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 238 KB

Asymmetric synthesis of putaminoxin, a phytotoxic macrolide from the cultured dinoflagellate Amphidinium sp., has been accomplished. Absolute configuration of putaminoxin was concluded to be 1 from comparison of the NMR data and [a] D values of synthetic and natural putaminoxin.