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Determination of tacticity of poly(hexyl α-chloroacrylate) by 13C NMR spectroscopy

✍ Scribed by C. P. Pathak; M. J. Patni; G. N. Babu


Book ID
105336248
Publisher
Wiley (John Wiley & Sons)
Year
1986
Tongue
English
Weight
138 KB
Volume
24
Category
Article
ISSN
0887-6258

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✍ V. N. Gogte; R. K. Nanda; A. A. Natu; V. S. Pandit; M. K. Sastry 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 283 KB

Oxazolidine derivatives of p-amino alcohols such as ephedrine have been resolved by -C NMR spedroscopy using Eu(hfc), as a chiral shift reagent. The method is quantitative in the determination of enantiomeric excess, and is advantageous where 'H NMR is of limited use owing, for example, to signitica