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Determination of Solvent Effects on Keto—Enol Equilibria of 1,3-Dicarbonyl Compounds Using NMR

✍ Scribed by Cook, A. Gilbert; Feltman, Paul M.


Book ID
115536122
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
92 KB
Volume
84
Category
Article
ISSN
0021-9584

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Substituent effects in keto-enol tautome
✍ M. Bassetti; G. Cerichelli; B. Floris 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 437 KB

The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h