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Determination of rate constants for the reaction of hydroxyl radicals with some purines and pyrimidines using sunlight

✍ Scribed by Jiju M. Joseph; C.T. Aravindakumar

Book ID
117331581
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
105 KB
Volume
42
Category
Article
ISSN
0165-022X

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## Abstract The hydrated electron (e^−^~aq~) and hydroxyl radical rate constants with 18 acrylate‐, methacrylate‐, crotonate‐, fumarate‐ and maleate esters are discussed. The constants approach the diffusion‐controlled limit. __k__(e^−^~aq~) and __k__(OH) change in opposite direction; if __k__(e^−^