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Rate Constant Determination for the Reaction of Hydroxyl and Glutathione Thiyl Radicals with Glutathione in Aqueous Solution †

✍ Scribed by Mezyk, Stephen P.


Book ID
118135808
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
292 KB
Volume
100
Category
Article
ISSN
0022-3654

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Rate constants for some reactions of fre
✍ Pichai Maruthamuthu; S. Padmaja; Robert E. Huie 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 443 KB 👁 1 views

The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.