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Determination of propagation rate constants using a pulsed laser technique

โœ Scribed by Davis, Thomas P.; O'Driscoll, Kenneth F.; Piton, Mark C.; Winnik, Mitchell A.

Book ID
126082006
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
439 KB
Volume
22
Category
Article
ISSN
0024-9297

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Evaluation of propagation rate constants
Evaluation of propagation rate constants for the free radical polymerization of methacrylonitrile by pulsed laser photolysis
โœ Devon A. Shipp; Trevor A. Smith; David H. Solomon; Graeme Moad ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 411 KB

## Abstract Propagation rate constants for the free radical polymerization of methacrylonitrile (MAN) have been obtained by pulsed laser photolysis (PLP). The temperature dependence of the propagation rate constants indicates a frequency factor of 10^(6,43 ยฑ 0,26)^ L ยท mol^โˆ’1^ ยท s^โˆ’1^ and an activa