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Determination of Free-Radical Propagation Rate Coefficient ofN-Vinylindole by the Pulsed-Laser Polymerization Method

โœ Scribed by Masataka Ohoka; Hideo Ohkita; Shinzaburo Ito; Masahide Yamamoto


Book ID
106000763
Publisher
Springer
Year
2004
Tongue
English
Weight
381 KB
Volume
51
Category
Article
ISSN
0170-0839

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Evaluation of propagation rate constants
โœ Devon A. Shipp; Trevor A. Smith; David H. Solomon; Graeme Moad ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 411 KB

## Abstract Propagation rate constants for the free radical polymerization of methacrylonitrile (MAN) have been obtained by pulsed laser photolysis (PLP). The temperature dependence of the propagation rate constants indicates a frequency factor of 10^(6,43 ยฑ 0,26)^ L ยท mol^โˆ’1^ ยท s^โˆ’1^ and an activa