Ruthenium shows promise for use as a chemical modifier for the determination of ultratrace quantities of lead in solution when compared with the popular and widely used palladium. There is experimental evidence that ruthenium reacts with lead in the graphite tube to form the intermetallic compound P
Determination of gold in ores by flame and graphite furnace atomic absorption spectrometry using a vanadium chemical modifier
✍ Scribed by C. García-Olalla; A.J. Aller
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 873 KB
- Volume
- 252
- Category
- Article
- ISSN
- 0003-2670
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✦ Synopsis
The determination of gold in ores by both flame and graphite furnace atomic absorption spectrometry a.t different analytical wavelengths are compared. Vanadyl chloride was shown to be effective as a chemical modifier for determining gold in the presence of heavy metals. A sensitivity of 1 pg I-' and a detection limit of 1 pg 1-l (or 0.1 pg 6 -1 in the original sample) were obtained. The best linear range was between 1 and 120 pg 1-l and a characteristic mass of 1 pg u:as obtained.
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