The use of the simplex procedure as a non-linear least-squares curve-fitting method is proposed for evaluation of equivalence points in sigmoidal and segmented titration curves. The application of this procedure to theoretical curves affected by different amounts of random noise indicates its effect
β¦ LIBER β¦
Determination of equivalence points of sigmoidal potentiometric titration curves
β Scribed by Greschonig, Herbert ;Glatter, Otto
- Book ID
- 105118082
- Publisher
- Springer-Verlag
- Year
- 1986
- Weight
- 358 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0344-838X
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## AKALYTICA CHIMICA ACTA alcncc point in a titration of this type cvcn thougli it c,an never do so in the "symmctrical" (isovalcnt) case. DERIVATION 01: A GIINElCAL EQUA'IIOX I:011 'THE 1KI~LEC'I'ION I'OIN'I' We shall consiclcr the general precipitation reaction ~Ilv"+ -1.. m:\~~-= l$,,A,, (I) +