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Determination of eigenvectors in DNA polymer spectroscopy by isotopic substitution

โœ Scribed by L. L. Van Zandt; V. K. Saxena

Book ID
101719755
Publisher
Wiley (John Wiley & Sons)
Year
1990
Tongue
English
Weight
416 KB
Volume
30
Category
Article
ISSN
0006-3525

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โœฆ Synopsis

SYNOPSIS

A simple relationship between frequency shifts to be expected in molecular vibrational spectra upon isotopic substitution and component values of eigenvectors is displayed. Application of this expression to the problem of force constant refinement is discussed in terms of a refinement algorithm developed some years ago to overcome particular problems associated with large molecular systems. Calculations of expected isotopic shifts have been calculated and are tabulated here for experimental reference.

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