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Determination of DNA by Use of the Molecular "Light Switch" Complex of Ru(bipy) 2 (dppz) 2+

✍ Scribed by Ling, Lian-Sheng ;He, Zhi-Ke ;Song, Gong-Wu ;Han, He-You ;Zhang, Hua-Shan ;Zeng, Yun-E


Publisher
Springer-Verlag
Year
2000
Weight
113 KB
Volume
134
Category
Article
ISSN
0344-838X

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Structure of the Complex of [Ru(tpm)(dpp
✍ Philip Waywell; Veronica Gonzalez; Martin R. Gill; Harry Adams; Anthony J. H. M. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 790 KB

## Abstract We report the synthesis of three new complexes related to the achiral [Ru(tpm)(dppz)py]^2+^ cation (tpm=tripyridazole methane, dppz=dipyrido[3,2‐__a__:2′,3′‐__c__]phenazine, py=pyridine) that contain an additional single functional group on the monodentate ancillary pyridyl ligand. Comp

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✍ Philip Waywell; Veronica Gonzalez; Martin R. Gill; Harry Adams; Anthony J. H. M. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 357 KB

The NMR-derived structure of an achiral… ] complex bound to duplex DNA confirms that it intercalates from the minor groove as described in the Full Paper by J. A. Thomas et al. on page 2407 ff. The structure also explains why the nature and position of a single functional group acts as an on/off sw