✦ LIBER ✦

Determination of daughter ion elemental compositions in charge separation reactions

✍ Scribed by Peter C. Vijfhuizen; Henk Van Der Schee; Johan K. Terlouw

Publisher: John Wiley and Sons
Year: 1977
Tongue: English
Weight: 208 KB
Volume: 12
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210120711

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✦ Synopsis

Abstract

It is shown that the elemental composition of a product ion generated from a multiply charged ion in a charge separation reaction can be determined with a double focusing instrument under conditions of high mass and energy resolution. Results for a number of charge separation reactions in benzylamine are briefly discussed.

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Dication dissociations of the five-membered nitrogen heterocycles (pyrrole, imidazole, pyrazole, 1,2,3-triazole, 1,2,4triazole and tetrazole) were investigated using charge separation mass spectrometry. Differences in the spectra for isomer pairs reflect an absence of C,N scrambling prior to fragmen