Determination of copper, manganese and nickel in biological samples and sea-water by flow injection on-line sorption preconcentration in a knotted reactor coupled with electrothermal atomic absorption spectrometry
β Scribed by Ivanova, Elissaveta; Benkhedda, Karima; Adams, Freddy
- Book ID
- 125492324
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 104 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0267-9477
- DOI
- 10.1039/A709150H
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A flow-injection on-I& adsorption precontentration flame atomic absorption spectrometric system for the detenninatian of copper was developed. The copper d~eth~ldith~~arba~ate chefate was adsorbed on the walls of a PTFE knotted reactor. The sorbed species was eluted by isobutyl methyl ketone at a fl
An automated robotic method for sample pretreatment was developed for copper determination in environmental and biological materials at the low microgram per gram level. The robotic station performing the preliminary operations as weighing of sample and acid digestion was coupled with the flowinject
ment factor of 47 in comparison with direct injection of 45 lL aqueous solution was obtained at a sampling frequency of 31 h β«1Χβ¬ . The detection limit (3 r) was found to be 2.8 ng L β«1Χβ¬ . The precision was 3% relative standard deviation (RSD) at the 0.2 lg L β«1Χβ¬ level (n β«Χ‘β¬ 11). The results obta