Determination of copper in seawater by adsorptive voltammetry with 1,2-dihydroxyanthraquinone-3-sulfonic acid
✍ Scribed by François Quentel; Catherine Elleouet; Christian Madec
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 580 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1040-0397
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✦ Synopsis
Abstract
A method is described for the determination of copper in seawater by adsorptive stripping voltammetry after accumulation of a 1,2‐dihydroxyanthraquinone‐3‐sulfonic acid (DASA) complex. The effects of various operational parameters (pH, ligand concentration, potential, and accumulation time) on the reduction current of the adsorbed chelate are discussed. A linear current concentration relationship was observed up to 5 × 10^−8^ M. The detection limit is 0.3 nM.
📜 SIMILAR VOLUMES
Cadmium and lead form 2-nitroso-1-naphthol-4-sulfonic acid-tetradecyldimethylbenzylammonium ion-associated complexes which are quantitatively adsorbed on microcrystalline naphthalene in the pH ranges 5.7-11.0 and 8.0-10.5, respectively. After filtration, the solid mass is shaken with 10 ml of 1 M hy