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Determination of constants of the Mark-Kuhn-Houwink equation using microamounts of polymers on the basis of microcolumn exclusion chromatography

✍ Scribed by Ye.Ye. Kever; L.Z. Vilenchik; E.S. Gankina; B.G. Belenkii

Book ID: 116048346
Publisher: Elsevier Science
Year: 1987
Weight: 154 KB
Volume: 29
Category: Article
ISSN: 0032-3950
DOI: 10.1016/0032-3950(87)90144-4

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In this work, we present values for the Mark-Houwink-Sakurada (MHS) and Stockmayer-Fixman (SF) constants for a series of homopolymers of para-substituted styrenes (4-X-styrene; X ϭ OCH 3 , OCH 2 CH 3 , CH 3 , F, Cl, and Br) in THF at room temperature. The respective values of K (in 10 Ϫ5 dL/g) and ␣