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The Effect of Uncertainties in the Kuhn-Mark-Houwink-Sakurada Constants on the Quantitative Analysis by Gel Permeation Chromatography

✍ Scribed by Deniz, Veli ;Güven, Olgun


Publisher
Wiley (John Wiley & Sons)
Year
1986
Tongue
English
Weight
268 KB
Volume
18
Category
Article
ISSN
0007-1641

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In this work, we present values for the Mark-Houwink-Sakurada (MHS) and Stockmayer-Fixman (SF) constants for a series of homopolymers of para-substituted styrenes (4-X-styrene; X ϭ OCH 3 , OCH 2 CH 3 , CH 3 , F, Cl, and Br) in THF at room temperature. The respective values of K (in 10 Ϫ5 dL/g) and ␣