Determination of atomic stress distribution in oriented polypropylene by infrared spectroscopy
β Scribed by Roylance, D. K. ;DeVries, K. L.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1971
- Tongue
- English
- Weight
- 203 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0449-2986
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An infrared method has been developed for the determination of the isotacticity of polypropylene in the 90-100~o range. The method requires the annealing of thin films a t 165-167Β°C. for 3 hr. in an inert at>mosphere, followed by slow cooling to room temperature. For approximate answers the ratio of
Attenuated total reflection-infrared (ATR-IR) spectroscopy and wide-angle x-ray diffraction (WAXD) were used to determine the macromolecular orientation of a series of six uniaxially oriented polypropylene sheets with elongations of 0% to 500%. The orientation functions were expressed as fractions o