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Determination of A0 for CD3Cl from the ν4 Raman band

✍ Scribed by Svend Brodersen


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
634 KB
Volume
71
Category
Article
ISSN
0022-2852

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The Raman spectrum of the Coriolis interacting u2, us bands of CD,CI was recorded with a resolution of cu 0.6 cm-'. Using the vibrational-rotational parameters of Yamada and Hirota, a computer simulation of the Raman contour was performed, yielding relative values of Raman polarizability derivatives

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The infrared spectrum in the range 900-1230 cm -1 including the fundamental bands ν 3 and ν 6 of CD 3 CN has been studied. The resolution attained was 0.0025 cm -1 in the measurement on the Bruker 120 HR Fourier spectrometer in Oulu. About 4000 lines were assigned in the ν 6 band. For the weak ν 3 b