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Determination and modeling of aqueous solubility of 4-position substituted benzoic acid compounds in a high-temperature solution

✍ Scribed by Sunsandee, Niti; Suren, Sira; Leepipatpiboon, Natchanun; Hronec, Milan; Pancharoen, Ura

Book ID
118446405
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
772 KB
Volume
338
Category
Article
ISSN
0378-3812

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Poly(acry1ic acid) (PAA) was decarboxylated in aqueous solution as a function of pH and ionic strength in the temperature range 10O-35O0C. Degradation kinetics were first order with respect to acid functionality. The rate of decarboxylation at high pH (E, = 51.1 kcall mol) was much slower than that