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Reactions of ortho-substituted benzanilides and related heterocyclic compounds in aqueous sulfuric acid solution

✍ Scribed by A. I. Donskikh; V. N. Kulagin; T. E. Nenasheva; Yu. V. Moiseev; G. E. Zaikov; G. M. Tseitlin


Book ID
112438713
Publisher
Springer
Year
1978
Tongue
English
Weight
406 KB
Volume
27
Category
Article
ISSN
1573-9171

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Kinetics and mechanisms of substitution
✍ P. Van Z. Bekker; W. Robb πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 545 KB

## Abstract The activation energy parameters for the reaction of PdX (X=Cl^βˆ’^, Br^βˆ’^) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each cas