Detection of vibrationally excited O2 in O2(a1Δg)–I mixture
✍ Scribed by Ivan O. Antonov; Valery N. Azyazov; Sergey Yu. Pichugin; Nikolay I. Ufimtsev
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 190 KB
- Volume
- 376
- Category
- Article
- ISSN
- 0009-2614
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## Abstract The effect of hydrogen on the concentration of singlet oxygen in the a^1^Δ~g~ and b^1^Σ states, generated from a microwave discharge in O~2~ and in an O~2~/Ar mixture, was studied in flow reactors. The addition of hydrogen, in a range of 0.01–1 of concentration of the O~2~, increased th
The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +