The Raman linewidths of the carbon-halogen stretching mode in several halobenzenes were measured as a function of temperature and in dilute cyclohexane solution\_ It was found that, as in an earlier investigation on haloalkanes, the vibrational relaxation efficiencies, pi;',, vary in the order Cl >
Detection of the relaxation of the stretching mode in thin liquid films
β Scribed by J.G.H. Joosten; H.M. Fijnaut
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 320 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The streuzhing mode in thin (50 nm), free, liquid fiJms has been e xamined by means of iaser intensity fluctuation sprc- toscopy (heterodyne configuration). The power density spectra of the scattered intensity fluctuaticms show mvrima ~ZX the MHz region, indicating the propagating character of the mode_ The peak frequencies are related to the surface tension of the f&u.
π SIMILAR VOLUMES
Velocity measurements have been made in thin films of liquid both in the wavy and wavefree &&es and in the entry region. nearly parabolic.
We have investigated the vibrational relaxation of the OH impurity stretch mode in amorphous SiO 2. At low temperatures, a short relaxation time of ~-10-l0 s is found that varies strongly across the inhomogeneously broadened absorption line. The inhomogeneous broadening is caused by a site-dependent