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Detection of a secondary isotope effect on partitioning of benzhydryl benzoate ion pairs

✍ Scribed by Murr, Brown L.; Donnelly, M. F.

Book ID
127334723
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
380 KB
Volume
92
Category
Article
ISSN
0002-7863

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RECENTLY2 it was discovered that in the trsns-5-methyl-2-cyclohexenyl Rnitrobensoate system internal return results in equilibration of the carbovl oxygen atoms at a rate greater than that of allylic rearrangement (racemization). This suggested that equilibration of carboul omgen atoms might be a us