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Detection and characterisation of a weakly bound dimer of allene and hydrogen fluoride by rotational spectroscopy

โœ Scribed by A.C. Legon; L.C. Willoughby

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
573 KB
Volume
143
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Rotational spectra have been detected in each of two low-energy vibrational states (A and B) for both allene...HF and allene.,.DF by pulsed-nozzle, FT microwave spectroscopy, Analysis of nuclear hype&e structure in the lo, eOOO transition of each state leads to the coupling constants D, HF for allene...HF and 1: and D,"d for allene...DF. Rotational constants A=9385(2), &3722.479(26) and C=2697.449(24) MHz determined for state A of allene...HF are interpreted in terms of an Lshaped hydrogen-bonded geometry for the dimer.

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