✦ LIBER ✦

Characterisation by rotational spectroscopy of a hydrogen-bonded dimer formed between H2O and HCN

✍ Scribed by Annette J. Fillery-Travis; A.C. Legon; L.C. Willoughby

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 420 KB
Volume: 98
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80225-5

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The rotational spectrum and structure of

The rotational spectrum and structure of the hydrogen-bonded dimer formed between methylenecyclopropane and HF

✍ Z. Kisiel; P.W. Fowler; A.C. Legon 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 355 KB

The hydrogen-bonded dimer between methylenecyclopropane and HF was observed and its rotational spectrum measured with a pulsed-nozzle Fourier-transform microwave spectrometer. Simultaneous analysis of the spectroscopic constants of HF and DF species of the dimer shows that the acid is attached in a

Detection and characterisation of a weak

Detection and characterisation of a weakly bound dimer of allene and hydrogen fluoride by rotational spectroscopy

✍ A.C. Legon; L.C. Willoughby 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 573 KB

Rotational spectra have been detected in each of two low-energy vibrational states (A and B) for both allene...HF and allene.,.DF by pulsed-nozzle, FT microwave spectroscopy, Analysis of nuclear hype&e structure in the lo, eOOO transition of each state leads to the coupling constants D, HF for allen

Identification and molecular geometry of

Identification and molecular geometry of a weakly bound dimer (H2O, HC1 in the gas phase by rotational spectroscopy

✍ A.C. Legon; L.C. Willoughby 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 374 KB

Rotntional transitions of (HzO,H~~CI) and (H20.H3'CI) have been observed and ssisned in the frequency rm\_ee 7-1s GHz\_ Values of the rotational constants Bo + 12, and Bo -Co. the centrifugal distortion constzmts D~and DJK\_ and the Cl nuclear quadrupole coupling constang %0 and xbb are reported for

Structural measurements of hydrogen-bond

Structural measurements of hydrogen-bonded van der Waals dimers and trimers by rotational coherence spectroscopy. 2,5-diphenyloxadiazole (PPD) with water

✍ Thomas Troxler; Philip G. Smith; Michael R. Topp 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 598 KB

Rotational coherence spectroscopy involving polarized, time-correlated single-photon counting techniques has been used to measure the excited-state structures of hydrogen-bonded complexes between PPD and water at the 1: 1 and I : 2 levels of aggregation. Structure determinations involved comparison

Pre-reactive Complexes in Mixtures of Wa

Pre-reactive Complexes in Mixtures of Water Vapour with Halogens: Characterisation of H2O⋅⋅⋅ClF and H2O⋅⋅⋅F2 by a Combination of Rotational Spectroscopy and Ab initio Calculations

✍ Stephen A. Cooke; Gina Cotti; Christopher M. Evans; John H. Holloway; Zbigniew K 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB 👁 2 views

Isolation of H2S…ClF in a pre-reactive m

Isolation of H2S…ClF in a pre-reactive mixture of H2S and ClF expanded in a coaxial jet and characterisation by rotational spectroscopy

✍ H.I. Bloemink; K. Hinds; J.H. Holloway; A.C. Legon 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 558 KB

The reaction between H2S and C1F was precluded and H2S... C1F isolated by a coaxial supersonic expansion of the gaseous components into the Fabry-P6rot cavity of a pulsed-nozzle, Fourier-transform microwave spectrometer. The ground-state rotational spectra of seven isotopomers of HzS... C1F were ana