Detailed Modeling of the Reaction of C 2 H 5 + O 2
β Scribed by Carstensen, Hans-Heinrich; Naik, Chitralkumar V.; Dean, Anthony M.
- Book ID
- 126429109
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 274 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
New ab initio calculations of the potential energy surface of the recombination reaction H β«Χβ¬ O 2 β«Χ(β¬ M) β HO 2 β«Χ(β¬ M), together with statistical unimolecular rate theory employing extensive classical trajectory calculations on this potential, allowed the characterization of thermally averaged an
CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120Β°C in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an