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Desymmetrization of meso -1,2-Diols via the Dynamic Kinetic Resolution of Its Monodichloroacetates

✍ Scribed by Cao, Jin-Li; Qu, Jin

Book ID
125547320
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
923 KB
Volume
75
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Desymmetrization of unsaturated meso-1,2
Desymmetrization of unsaturated meso-1,2-diols via an intramolecular haloetherification of ene acetals: A remarkable kinetic control
✍ Hiromichi Fujioka; Yasushi Nagatomi; Naoyuki Kotoku; Hidetoshi Kitagawa; Yasuyuk πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 248 KB

Haloetherification reaction of the chiral ene acetals derived from unsaturated meso-1,2-diols and chiral non-racemic norbornene aldehyde proceeded in an intramolecular manner with an unexpectedly high kinetic control. This method has been successfully employed for the desymmetrization of unsaturated