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Desymmetrization of 1,4-Dien-3-ols and Related Compounds via Ueno−Stork Radical Cyclizations

✍ Scribed by Villar, Félix; Equey, Olivier; Renaud, Philippe


Book ID
126422746
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
112 KB
Volume
2
Category
Article
ISSN
1523-7060

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Radical Cyclization of Fluorinated 1,3-D
✍ Mehmet Yılmaz; E. Vildan Burgaz Yılmaz; A. Tarık Pekel 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 214 KB

## Abstract Radical cyclizations of fluorinated 1,3‐dicarbonyl compounds with dienes mediated by Mn(OAc)~3~ afforded 4,5‐dihydrofurans containing difluoroacetyl, trifluoroacetyl, or heptafluorobutanoyl groups in good‐to‐excellent yields. Additionally, 2‐(difluoromethyl)‐4,5‐dihydrofurans and a 4,7‐