Desulfurization of Benzo[b]thiophene by S/Ru Exchange: Formation and Structure of the Cluster [Ru3(CO)8(C8H6)]
✍ Scribed by Dr. Alejandro J. Arce; Ysaura De Sanctis; Arquímedes Karam; Prof. Antony J. Deeming
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 391 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip
## 211. Intramolecular Site Exchange of Carbonyl Ligands in the Cluster Compounds Nonacarbonyl{p,-[q3-( 1,3,5-trithiane)])triruthenium ([ Ru,(C O),{,u ,-(q 3-C3H,S3)} I) and (tevt-But yl1socyanide)octacarbonyl-{p3-[q3-( 1,3,5-trithiane)]) triruthenium ([Ru,(t-BuNC)(CO),{p,-(q3-C,~S,)}])