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Design, Synthesis, and Stereochemical Evaluation of a Novel Chiral Amine–Palladacycle

✍ Scribed by Yi Ding; Yongxin Li; Yi Zhang; Sumod A. Pullarkat; Pak-Hing Leung

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
887 KB
Volume
2008
Category
Article
ISSN
1434-1948

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✍ Yi Ding; Yi Zhang; Yongxin Li; Sumod A. Pullarkat; Paul Andrews; Pak-Hing Leung 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 465 KB 👁 2 views

## Abstract A novel amine ligand, 1‐(2,5‐dimethylphenyl)‐__N__,__N__,2,2‐tetramethylpropan‐1‐amine, was synthesized in six steps from commercially available __p__‐xylene. Direct __ortho__‐palladation of this amine ligand proceeded readily to form the racemic dimeric complex. The palladacycle struct