A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.
Design of a high-pressure ebulliometer, with vapor-liquid equilibrium results for the systems CHF2Cl + CF3CH3and CF3CH2F + CH2F2
โ Scribed by L. A. Weber; A. M. Silva
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 684 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0195-928X
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๐ SIMILAR VOLUMES
## Abstract The intermolecular interaction energy curves of CH~3~OCH~3~๏ฃฟCH~2~F~2~, CF~3~OCH~3~๏ฃฟCH~2~F~2~, CF~3~OCF~3~๏ฃฟCH~2~F~2~, CH~3~OCH~3~๏ฃฟCHF~3~, CF~3~OCH~3~๏ฃฟCHF~3~, and CF~3~OCF~3~๏ฃฟCHF~3~ complexes were calculated by the MP2 level __ab initio__ molecular orbital method using the 6โ311G\*\* basi
Data on the tropospheric degradation of proposed substitutes for ozone depleting CFCs were obtained by conducting photochemical oxidation studies of HCFCs and HFCs using long path Fourier transform infrared spectroscopy. The hydrogen abstraction reactions were initiated using C1 radicals rather than