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Design and synthesis of 6-amino-5-oxo-1,2,3,5-tetrahydro-3-indolizinecarboxylic acids as β-sheet peptidomimetics

✍ Scribed by Xiaojun Zhang; Aaron C. Schmitt; Carl P. Decicco

Book ID
104252568
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
217 KB
Volume
43
Category
Article
ISSN
0040-4039

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Versatile synthesis of chiral 2-substituted-5-oxo-1,2,3,4-tetrahydro-5H-1,4-benzodiazepines as novel scaffolds for peptidomimetic building
✍ Susana Herrero; M.Teresa Garcı́a-López; Edurne Cenarruzabeitia; Joaquı́n Del Rı́ 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 206 KB

The stereocontrolled synthesis of phenylalanine and tryptophan derived 5-oxo-1,2,3,4-tetrahydro-5H-1,4-benzodiazepine derivatives is described. This new methodology involves a modified Strecker reaction of N-Boc protected amino aldehydes and methyl anthranilate, reduction of the resulting a-amino ni