When optimizing a capillary electrophoresis/electrospray ionization mass spectrometry (CE/ESI-MS) system, consideration has to be given not only to the separation but also to the electrospray stability. Methods developed for CE/UV analysis of drugs and peptides were considered and modified to be sui
Derivation of an interface condition for interfaces that possess mass capacity
β Scribed by Yi-Hsu Ju; Wen-Chien Lee
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 581 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0009-2509
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β¦ Synopsis
The interface between adjoining layers in a multi-layer medium is usually considered to have zero thickness. Actually, although very thin, the interface may accumulate mass due to the so-called secondary phenomena occurring at the interface in a diffusion process. In this work, a regular perturbation technique is used to find an interface condition which takes into account the immobilization reaction which may occur with diffusion in a multi-layer medium. By the correct adjustment of parameters, the new interface condition can be reduced to the classical one. An example is given to illustrate the application of the new interface condition and an experimental method is suggested to determine the physical properties of a reaction membrane.
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An interface for capillary electrophoresis (CE) and inductively coupled plasma mass spectrometry (ICP-MS) is developed with a commercial ultrasonic nebulizer. The CE ground path was provided through a coaxial liquid electrolyte flow surrounding the CE capillary. To accommodate this dual capillary ar