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Deracemization of a Macrocyclic 1,1′-Biisoquinoline

✍ Scribed by Gerald Dyker; Wolfgang Stirner; Gerald Henkel; Peter R. Schreiner

Book ID
102258768
Publisher
John Wiley and Sons
Year
2008
Tongue
German
Weight
432 KB
Volume
91
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The macrocyclic biisoquinoline 14 was synthesized in just four preparative steps starting from the simple biscarboxaldehyde 8. The interaction with camphorsulfonic acid induces an acid‐catalyzed partial deracemization.

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