Deprotonation of unsaturated fluoroethers, CH2=CHCH2OCF2CHXCF3and CH≡CCH2OCF2CHXCF3(X=COF and SO2F)
✍ Scribed by V. G. Andreev; A. F. Kolomiets; A. F. Eleev; G. A. Sokol'skii
- Book ID
- 112447405
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 289 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine
## Abstract The intermolecular interaction energy curves of CH~3~OCH~3~CH~2~F~2~, CF~3~OCH~3~CH~2~F~2~, CF~3~OCF~3~CH~2~F~2~, CH~3~OCH~3~CHF~3~, CF~3~OCH~3~CHF~3~, and CF~3~OCF~3~CHF~3~ complexes were calculated by the MP2 level __ab initio__ molecular orbital method using the 6‐311G\*\* basi