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Deprotonation of the peptide NH groups and diastereoselective hydrogenation of N-acetyl-α,-dehydrodipeptides

✍ Scribed by I. N. Lisichkina; A. G. Ivanova; A. S. Peregudov; V. M. Belikov


Book ID
110301162
Publisher
Springer
Year
2001
Tongue
English
Weight
280 KB
Volume
50
Category
Article
ISSN
1573-9171

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The characteristic coUisionLinduced dissociations of (M -HI-ions of dipeptides and tripeptides involve proton transfer to the carboxylate centre as a prelude to fragmentation. Dipeptides show the process + NH,C(R')=C=O (R = H or alkyl) while tripeptides show the analogous processes NH,CH(R')CONHCH(R