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Deprotonation of 5,6-Dihydro-5-methylene-4H-1,2-oxazines and Regioselective Reactions with Electrophiles

✍ Scribed by Unger, Clemens ;Zimmer, Reinhold ;Reißig, Hans-Ulrich ;Würthwein, Ernst-Ulrich


Publisher
Wiley (John Wiley & Sons)
Year
1991
Tongue
English
Weight
768 KB
Volume
124
Category
Article
ISSN
0009-2940

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1 ,ZOxazines, bis(trimethylsily1)amino-substituted / Hydrogenolysis / Deprotonation / Alkylation / Deuteration 1,2-Oxazine 1 was converted into an unusual condensation product 5 by treatment with tetra-n-butylammonium fluoride. The hydrogenolysis of 1 with Pd/C as catalyst provided the expected prim