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Dependence of the27Al and31P NMR chemical shifts in alumophosphates on the composition of the second coordination sphere

✍ Scribed by M. A. Fedotov; I. L. Mudrakovskii; V. M. Mastikhin; V. P. Shmachkova; N. S. Kotsarenko


Book ID
112449248
Publisher
Springer
Year
1987
Tongue
English
Weight
264 KB
Volume
36
Category
Article
ISSN
1573-9171

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Solvation effects on the 31P-nmr chemica
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The effects of organic solvents on the 3'P-mr chemical shifts of various phosphate diesters have been investigated in water and mixed-organic solvent systems. The addition of organic solvents to cyclic phosphates and to diethyl phosphate causes large upfield shifts of the phosphorus resonance which