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SUBSTITUENT EFFECTS ON THE 31 P NMR CHEMICAL SHIFTS OF 1-AMINO- AND 1-HYDROXY-ALKYLPHOSPHONIC ACIDS

✍ Scribed by Głowacki, Zdzisław; Hoffmann, Maria; Topolski, Marek; Rachoń, Janusz


Book ID
118278409
Publisher
Taylor and Francis Group
Year
1991
Tongue
English
Weight
278 KB
Volume
60
Category
Article
ISSN
1042-6507

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✍ Zdzisław Glowacki; Maria Hoffmann 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 208 KB

## Abstract ^13^C chemical shifts and ^31^P,^13^C coupling constants are reported for nine 1‐hydroxyalkylphosphonic and two additional phosphonic acids. The α‐substituent‐induced chemical shifts (α‐SCS) of the phosphonate group were calculated and their non‐additivity was observed. Good linear corr