The dependence of the retention factor of compounds on the average pressure was theoretically considered for binary gas mixture on the basis of a new form of Langmuir adsorption equation taking into consideration the substitution reaction of the adsorbed molecule of the carrier gas for the adsorbed
Dependence of the width of the chromatographic zone on retention time in capillary gas chromatography
β Scribed by V. G. Berezkin; V. E. Shiryaeva; T. P. Popova
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 154 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract In capillary gasβsolid chromatography where interactions between solute and carrier gas and adsorption of the solute on the surface of the adsorbent are considered to be imperfect, it has been shown that chromatographic retention is determined largely by adsorption processes. It has bee
## Abstract A previously established model of a system of seriesβcoupled columns, incorporating the effects of temperature and mobile phase compressibility, is generalized to take the temperature dependence of the mobile phase viscosity coefficient into account. Expressions are reported for the lin
In on-column or in splitless injection with recondensation of the solvent, the length of the flooded zone in the column inlet depends primarily on the wettability of the internal wall of the inlet. For columns with a coated inlet this explains why peak distortion due to band broadening in space by a