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The influence of the carrier gas on retention in capillary gas-solid chromatography

โœ Scribed by Berezkin, Viktor G. ;Malyukova, Irina V. ;Alishoev, Victor R. ;de Zeeuw, Jaap

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
394 KB
Volume
19
Category
Article
ISSN
0935-6304

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โœฆ Synopsis

Abstract

In capillary gasโ€solid chromatography where interactions between solute and carrier gas and adsorption of the solute on the surface of the adsorbent are considered to be imperfect, it has been shown that chromatographic retention is determined largely by adsorption processes. It has been established that correlation relationships k(P~2~)=A k(P~1~) + B, where k is the retention factor, and A and B are equation constants, was valid for use of different carrier gases P~1~ and P~2~. Column efficiency could be improved by use of carbon dioxide. The advantages of using carbon dioxide as the carrier gas were investigated.

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