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Dependence of the preexponential factor on temperature

✍ Scribed by J. M. Criado; L. A. Pérez-Maqueda; P. E. Sánchez-Jiménez

Publisher
Springer Netherlands
Year
2005
Tongue
English
Weight
130 KB
Volume
82
Category
Article
ISSN
0022-5215

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Predicting the preexponential temperatur
Predicting the preexponential temperature dependence of bimolecular metathesis reaction rate coefficients using transition state theory
✍ N. Cohen 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 681 KB

The thermochemical kinetics formulation of conventional transition state theory for bimolecular reactions allows for a separate contribution from each degree of freedom (translation, rotation, vibration, etc.) in the activated complex to the entropy and heat capacity of activation, and thus to the p