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Density functional study of ortho-substituted phenyl cations in polar medium and in the gas phase

โœ Scribed by Sergey V. Bondarchuk; Boris F. Minaev

Book ID
113533141
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
852 KB
Volume
389
Category
Article
ISSN
0301-0104

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Metastable ion study of substituted cycl
Metastable ion study of substituted cyclopentadienylmanganese cations in the gas phase
โœ Dmitri V. Zagorevskii; Yurii S. Nekrasov; John L. Holmes ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 663 KB

The behavior of some substituted cyclopentadienylmanganese ions has been studied by tandem mass spectrometry. This metastable ion study showed that only C5H5Mn(+) and (C5H4CN)Mn(+) ions retain their nido-cluster structure (1), which is characterized by a simple metal-ligand bond cleavage. Other subs