The generation of singlet oxygen by a photochemical pathway, involving the excited state of a pentaammine Ru(II) complex ,:ontaining an N-substituted 4-cyanopyridine ligand and molecular oxygen in aqueous solution, is reported in this work. A :wo-step degradation process occurs by virtue of the acti
✦ LIBER ✦
Density functional studies of influences of Ni triad metals and solvents on oxidative addition of MeI to [M(CH3)2(NH3)2] complexes and C–C reductive elimination from [M(CH3)3(NH3)2I] complexes
✍ Scribed by Fatemeh Niroomand Hosseini; Alireza Ariafard; Mehdi Rashidi; Gholamhassan Azimi; S. Masoud Nabavizadeh
- Book ID
- 116680140
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 639 KB
- Volume
- 696
- Category
- Article
- ISSN
- 0022-328X
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As part of studies aimed at delineating the mechanism of the rhodium(III) complexes 2a,b and 3a,b have been characterized by 31 P-, 1 H-, and 13 C-NMR spectrometry, as rhodium complex-catalyzed hydroamination of olefins, the model complexes [Rh(PNP)R] (R = CH 3 1a, C 6 H 5 1b) have well as by EI mas