The excess molar enthalpies for (butanenitrile + benzene, or methylbenzene, or 1,2-dimethylbenzene, or 1,3-dimethylbenzene, or 1,4-dimethylbenzene, 1,3,5trimethylbenzene, or ethylbenzene) have been determined at T = 298.15 K. The excess molar enthalpies ranged from a minimum of -57 J • mol -1 for be
Densities, refractive indices, and derived properties of (cyclohexane, orn-heptane +  an aromatic hydrocarbon) atT =  298.15 K
✍ Scribed by C. Dı́az; B. Orge; G. Marino; J. Tojo
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 504 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0021-9614
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✦ Synopsis
This paper reports experimental densities and refractive indices of (cyclohexane, or n-heptane + o-xylene, or m-xylene, or p-xylene, or ethylbenzene) over the whole composition range at T = 298.15 K and at atmospheric pressure. Excess molar volumes and changes of refractive indices were calculated from the experimental data obtained. Partial excess molar volumes were also computed for all the mixtures studied. The results were fitted by means of the Redlich-Kister equation with the aid of F-test to optimize the number of parameters. Measurements were compared with other literature values. Different empirical and semiempirical models were applied in order to estimate physical property values and good agreement was obtained with experimental results.
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The excess molar enthalpies of (benzonitrile + benzene, or methylbenzene, or 1,2-dimethylbenzene, or 1,3-dimethylbenzene, or 1,4-dimethylbenzene, or 1,3,5trimethylbenzene, or ethylbenzene) have been determined at T = 298.15 K. The excess molar enthalpies range from -10 J • mol -1 for methylbenzene t
Densities, speeds of sound and refractive indices have been measured for (n-hexane + cyclohexane + 1-hexanol) and its corresponding binaries at T = 298.15 K. In addition, ideal isentropic compressibilities were calculated from the speeds of sound, densities, and literature heat capacities and cubic
A flow microcalorimeter of the Picker design was used to measure excess molar enthalpies H E m at the temperature 298.15 K over the whole composition range of several binary liquid mixtures formed from an alkanoic acid and either n-heptane, or cyclohexane, or benzene. The alkanoic acids selected wer
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